Publications

Publications acknowledging the SPP 2102

"This work was supported by Deutsche Forschungsgemeinschaft [DFG, Priority Program SPP 2102 “Light-controlled reactivity of metal complexes” (grant number)]."

2021

P. Pinter, J. Soellner, T. Strassner*,
Organometallics 2021, in press.
Photophysical Properties of Phosphorescent Mono- and Bimetallic Platinum(II) Complexes with C^C* Cyclometalating NHC Ligands
[DOI: 10.1021/acs.organomet.0c00790]

S. Witzel, A. S. K. Hashmi, J. Xie*,
Chem. Rev. 2021, in press.
Light in Gold Catalysis
[DOI: 10.1021/acs.chemrev.0c00841]

I. Maisuls, C. Wang, M. E. Gutierrez Suburu, S. Wilde, C. G. Daniliuc, D. Brünink, N. Doltsinis, S. Ostendorp, G. Wilde, J. Kösters, U. Resch-Genger*, C. A. Strassert*,
Chem. Sci. 2021, in press.
Ligand-controlled and nanoconfinement-boosted luminescence employing Pt(II) and Pd(II) complexes: From color-tunable aggregation-enhanced dual emitters towards self-referenced oxygen reporters
[DOI: 10.1039/D0SC06126C]

M. Heindl, J. Hongyan, S.-A. Hua, M. Oelschlegel, F. Meyer, D. Schwarzer, L. González*,
Inorg. Chem., 2021, in press.
Excited-State Dynamics of [Ru(S–Sbpy)(bpy)2]2+ to Form Long-Lived Localized Triplet States
[DOI: 10.1021/acs.inorgchem.0c03163]

P. Hahn, S. Ullmann, A. Kahnt, B. Abel, B. Kersting*,
Inorg. Chim. Acta 2021, 514, 119983.
Synthesis, Structures and Luminescence Properties of Dinuclear Nd, Eu, Tb, and Yb Complexes supported by a Pendant Picolyl-Imine Calix[4]arene Ligand
[DOI: 10.1016/j.ica.2020.119983]

J. Stubbe, N. I. Neuman, R. McLellan, M. G. Sommer, M. Nößler, J. Beerhues, R. E. Mulvey, B. Sarkar*,
Angew. Chem. Int. Ed., 2021, 60, 499-506.
Isomerization Reactions in Anionic Mesoionic Carbene-Borates and Control of Properties and Reactivities in the Resulting CoII Complexes through Agostic Interactions
[DOI: 10.1002/anie.202013376]

2020

M. Neugebauer, S. Schmitz, N. Doltsinis*, D. Brünink, A. Klein*,
New J. Chem. 2020, in press.
Dynamics of the efficient cyclometalation of the undercoordinated organoplatinum complex [Pt(cod)(neoPh)]+ (neoPh = 2-methyl-2-phenylpropyl)
[DOI: NJ-ART-09-2020-004811.R1]

C. Laube*, J. Taut, J. Kretzschmar, S. Zahn, W. Knolle, S. Ullman, A. Kahnt, B. Kersting*, B. Abel*,
Inorg. Chem. Front. 2020, in press.
Light Controlled Oxidation by Supramolecular Zn(II) Schiff-base Complexes
[DOI: 10.1039/D0QI00980F]

T. Bens, P. Boden, P. Di Martino-Fumo, J. Beerhues, U. Albold, S. Sobottka, N. I. Neuman, M. Gerhards*, B. Sarkar*,
Inorg. Chem. 2020, 59, 15504−15513.
Chromium(0) and Molydenum(0) Complexes with a Pyridyl-Mesoionic Carbene Ligand: Structural, (Spectro)electrochemical, Photochemical, and Theoretical Investigations
[DOI: 10.1021/acs.inorgchem.0c02537]

K. Heinze*, O. Wenger*,
Inorg. Chem. 2020, 59, 14627-14628.
Light-Controlled Reactivity of Metal Complexes (editorial)
[DOI: 10.1021/acs.inorgchem.0c02791]

S. Straub, J. Stubbe, J. Lindner, B. Sarkar, P. Vöhringer*,
Inorg. Chem. 2020, 59, 14629-14642.
Vibrational Relaxation Dynamics of an Azido–Cobalt(II) Complex from Femtosecond UV-Pump/MIR-Probe Spectroscopy and Model Simulations with Ab Initio Anharmonic Couplings
[DOI: 10.1021/acs.inorgchem.0c00553]

J.P. Zobel, O.S. Bokareva, P. Zimmer, C. Wölper, M. Bauer, L. González*,
Inorg. Chem. 2020, 59, 14666–14678.
Intersystem Crossing Dynamics in an Fe(II) N-heterocyclic carbene Photosensitizer
[DOI: 10.1021/acs.inorgchem.0c02147]

P. Dierks, A. Päpcke, B. Altenburger, O.S. Bokareva, T. Reuter, K. Heinze, O. Kühn, S. Lochbrunner, M. Bauer*,
Inorg. Chem. 2020, 59, 14746–14761.
Ground and excited state properties of iron(II) complexes linked to organic chromophores
[DOI: 10.1021/acs.inorgchem.0c02039]

M. Rentschler, M.-A. Schmid, W. Frey, S. Tschierlei*, M. Karnahl*,
Inorg. Chem. 2020, 59,14762-14771.
Multidentate Phenanthroline Ligands Containing Additional Donor Moieties and Their Resulting Cu(I) and Ru(II) Photosensitizers: A Comparative Study
[DOI: 10.1021/acs.inorgchem.9b03687]

N. Lüdtke, J. Föller, C. M. Marian*,
Phys. Chem. Chem. Phys. 2020, 22, 23530 - 23544
Understanding the luminescence properties of Cu(I) complexes: A quantum chemical perusal
[DOI: 10.1039/D0CP04654J]

M. Cnudde, D. Brünink, N. L. Doltsinis, C. A. Strassert*,
Inorg. Chim. Acta 2020, in press.
Tetradentate N^N°N^N-type luminophores for Pt(II) complexes: Synthesis, photophysical and quantum-chemical investigation
[DOI: 10.1016/j.ica.2020.120090]

M. Krause, R. von der Stück, D. Brünink, S. Buss, N. L. Doltsinis, C. A. Strassert, A. Klein*,
Inorg. Chim. Acta 2020, in press.
Platinum and Palladium Complexes of Tridentate -C^N^N (Phen-ide)-pyridine-thiazol Ligands – A case study involving spectroelectrochemistry, photoluminescence spectroscopy and TD-DFT calculations
[DOI: 10.1016/j.ica.2020.120090]

P. Hahna, S. Ullmann, A. Kahnt, B. Abel, B. Kersting*,
Inorg. Chim. Acta 2020, 514, 119983.
Synthesis, structures and luminescence properties of dinuclear Nd, Eu, Tb, and Yb complexes supported by a pendant picolyl-imine calix[4]arene ligand
[DOI: 10.1016/j.ica.2020.119983]

Y. Vukadinovic, L. Burkhardt, A. Päpcke, A. Miletic, L. Fritsch, B. Altenburger, R. Schoch, A. Neuba, S. Lochbrunner, M. Bauer*,
Inorg. Chem. 2020, 59, 8762–8774.
When Donors turn into Acceptors: Ground and excited state properties of Fe(II) complexes with amin-substituted tridentate bis-imidazol-2-ylidene pyridin ligands
[DOI: 10.1021/acs.inorgchem.0c00393]

J. Sun, J. Abbenseth, H. Verplancke, M. Diefenbach, B. de Bruin, D. Hunger, C. Würtele, J. van Slageren, M. C. Holthausen*, S. Schneider*,
Nat. Chem. 2020, 12, 1054-1059.
A platinum(II) metallonitrene with a triplet ground state
[DOI: 10.1038/s41557-020-0522-4]

S. Ullmann, P. Hahn, P. Mini, K. L. Tuck, A. Kahnt, B. Abel, M. E. Gutierrez Suburu, C. A. Strassert, B. Kersting*,
Dalton Trans. 2020, 49, 11179-11191.
Mixed-ligand lanthanide complexes supported by ditopic bis(imino-methyl)-phenol/calix[4]arene macrocycles: synthesis, structures, and luminescence properties of [Ln2(L2)(MeOH)2] (Ln = La, Eu, Tb, Yb)
[DOI: 10.1039/D0DT02303E]

A. Winter, M. Sittig, U. S. Schubert*,
Inorg. Chim. Acta 2020, 510, 119747
Dithiafulvenyl-equipped Ru(II) bis-terpyridine complexes – Synthesis, photophysical and electrochemical properties
[DOI: 10.1016/j.ica.2020.119747]

S. Flesch, L.I. Domenianni, P. Vöhringer*,
Phys. Chem. Chem. Phys. 2020, 22, in press.
Probing the primary processes of a triazido-cobalt(III) complex with femtosecond vibrational and electronic spectroscopies. Photochemical selectivity and multi-state reactivity
[DOI: 10.1039/D0CP04865H]

T. Unruh, P. Vöhringer*,
Z. Phys. Chem. 2020, 234, 1549-1566.
Thermal isomerization of [Co(acac)2(N3)(py)] in liquid solution studied by time-resolved Fourier-transform infrared spectroscopy
[DOI: 10.1515/zpch-2020-0006]

J. Kalmbach, C. Wang, Y. You, C. Förster, H. Schubert, K. Heinze*, U. Resch-Genger*, M. Seitz*,
Angew. Chem. Int. Ed. 2020, 59, 18804-18808.
Near-IR to Near-IR Upconversion Luminescence in Molecular Chromium Ytterbium Salts
[DOI: 10.1002/anie.202007200][DOI: 10.1002/ange.202007200]

S. Garbe, M. Krause, A. Klimpel, I. Neundorf, P. Lippmann, I. Ott, D. Brünkink, C. A. Strassert, N. L. Doltsinis, A. Klein*,
Organometallics 2020, 39, 746‒756.
Cyclometalated Pt Complexes of CNC Pincer Ligands: Luminescence and Cytotoxic Properties
[DOI: 10.1021/acs.organomet.0c00015]

I. O. Koshevoy*, M. Krause, A. Klein*,
Coord. Chem. Rev. 2020, 405, 213094 (1‒17).
Non-Covalent Intramolecular Interactions through Ligand-Design Promoting Efficient Luminescence from Transition Metal Complexes
[DOI: 10.1016/j.ccr.2019.213094]

Y. Yang, J. Brückmann, W. Frey, S. Rau, M. Karnahl*, S. Tschierlei*,
Chem. Eur. J. 2020, in press.
Electron storage capability and singlet oxygen productivity of a Ru(II) photosensitizer containing a fused naphthaloylenebenzene moiety at the 1,10-phenanthroline ligand
[DOI: 10.1002/chem.202001564]

M. Gernert, L. Balles-Wolf, F. Kerner, U Müller, A. Schmiedel, M. Holzapfel, C. M. Marian, J. Pflaum, C. Lambert, A. Steffen*,
J. Am. Chem. Soc. 2020, 142, 8897–8909.
Cyclic (amino)(aryl)carbenes (CAArCs) enter the field of chromophore ligands - Expanded π system leads to unusually deep red emitting CuI compounds
[DOI: 10.1021/jacs.0c02234]

M. Dorn, J. Kalmbach, P. Boden, A. Päpcke, S. Gómez, C. Förster, F. Kuczelinis, L. M. Carrella, L. Büldt, N. Bings, E. Rentschler, S. Lochbrunner, L. González, M. Gerhards*, M. Seitz*, K. Heinze*,
J. Am. Chem. Soc. 2020, 142, 7947–7955.
A vanadium(III) complex with blue and NIR-II spin-flip luminescence in solution
[DOI: 10.1021/jacs.0c02122]

L. Suntrup, F. Stein, J. Klein, A. Wilting, F. G. L. Parlane, C. M. Brown, J. Fiedler, C. P. Berlinguette, I. Siewert, B. Sarkar*,
Inorg. Chem. 2020, 59, 4215-4227.
Rhenium Complexes of Pyridyl-Mesoionic Carbenes: Photochemical Properties and Electrocatalytic CO2 Reduction
[DOI: 10.1021/acs.inorgchem.9b02591]

P. M. Becker, C. Förster, L. M. Carrella, P. Boden, D. Hunger, J. van Slageren, M. Gerhards, E. Rentschler, K. Heinze*,
Chem. Eur. J. 2020, 26, 7199-7204.
Spin Crossover and Long-lived Excited States in a Reduced Molecular Ruby
[DOI: 10.1002/chem.202001237]

J. Moll, C. Wang, A. Päpcke, C. Förster, U. Resch-Genger, S. Lochbrunner, K. Heinze*,
Chem. Eur. J. 2020, 26, 6820-6832.
Green Light Activation of Push-Pull Ruthenium(II) Complexes
[DOI: 10.1002/chem.202000871]

M. Rentschler, S. Iglesias, M.-A. Schmid, C. Liu, S. Tschierlei, W. Frey, X. Zhang, M. Karnahl*, D. Moonshiram*,
Chem. Eur. J. 2020, 26, 9527-9536.
The coordination behaviour of Cu(I) photosensitizers bearing multidentate ligands investigated by X-ray absorption spectroscopy
[DOI: 10.1002/chem.201905601]

S.-A. Hua, M. Cattaneo, M. Oelschlegel, M. Heindl, L. Schmid, S. Dechert, O. S. Wenger, I. Siewert*, L. González*, F. Meyer*,
Inorg. Chem. 2020, 59, 4972-4984.
Electrochemical and Photophysical Properties of Ruthenium(II) Complexes Equipped with Sulfurated Bipyridine Ligands
[DOI: 10.1021/acs.inorgchem.0c00220]

S. Sobottka, M. Nößler, A. L. Ostericher, G. Hermann, N. Z. Subat, J. Beerhues, M. Behr‐van der Meer, L. Suntrup, U. Albold, S. Hohloch, J. C. Tremblay, B. Sarkar*,
Chem. Eur. J. 2020, 26, 1314-1327.
Tuning PtII-Based Donor–Acceptor Systems through Ligand Design: Effects on Frontier Orbitals, Redox Potentials, UV/Vis/NIR Absorptions, Electrochromism, and Photocatalysis
[DOI: 10.1002/chem.201903700]

A. Winter, U. S. Schubert*,
ChemCatChem 2020, 12, 2890-2941.
Metal‐Terpyridine Complexes in Catalytic Application – A Spotlight on the Last Decade
[DOI: 10.1002/cctc.201902290]

A. Päpcke, A. Friedrich, S. Lochbrunner*,
J. Phys.: Condens. Matter 2020, 32, 153001.
Revealing the initial steps in homogeneous photocatalysis by timeresolved spectroscopy
[DOI: 10.1088/1361-648X/ab5ed1]

K. J. Endres, K. Barthelmes, A. Winter, R. Antolovich, U. S. Schubert*, C. Wesdemiotis*,
Rapid. Commun. Mass. Spec. 2020, 34, e8717.
Collision cross‐section analysis of self‐assembled metallomacrocycle isomers and isobars via ion mobility mass spectrometry
[DOI: 10.1002/rcm.8717]

T. O. Paulisch, F. Strieth-Kalthoff, C. Henkel, L. Pitzer, D. M. Guldi*, F. Glorius*,
Chem. Sci. 2020, 11, 731-736.
Chain propagation determines the chemo- and regioselectivity of alkyl radical additions to C–O vs. C–C double bonds
[DOI: 10.1039/c9sc04846d]

R. Giereth, A. K. Mengele, W. Frey, M. Kloß, A. Steffen, M. Karnahl*, S. Tschierlei*,
Chem. Eur. J. 2020, 26, 2675-2684.
Copper(I) Phosphinooxazoline Complexes: Impact of the Ligand Substitution and Steric Demand on the Electrochemical and Photophysical Properties
[DOI: 10.1002/chem.201904379]

2019

C. Dee, F. Zinna, W. R. Kitzmann, G. Pescitelli, K. Heinze*, L. Di Bari*, M. Seitz*,
Chem. Commun. 2019, 55, 13078-13081.
Strong Circularly Polarized Luminescence of an Octahedral Chromium(III) Complex
[DOI: 10.1039/c9cc06909g]

S. Treiling, C. Wang, C. Förster, F. Reichenauer, J. Kalmbach, P. Boden, J. P. Harris, L. Carrella, E. Rentschler, U. Resch-Genger, C. Reber, M. Seitz, M. Gerhards, K. Heinze*,
Angew. Chem. 2019, 131, 18243-18253; Angew. Chem. Int. Ed. 2019, 58, 18075-18085.
Luminescence and Light-driven Energy and Electron Transfer from an Exceptionally Long-lived Excited State of a Non-innocent Chromium(III) Complex
[DOI: 10.1002/anie.201909325] [DOI: 10.1002/ange.201909325]

A. Winter, P. Endres, E. Schröter, M. Jäger, H. Görls, C. Neumann, A. Turchanin, U. S. Schubert*,
Molecules 2019, 24, 4446.
Towards Covalent Photosensitizer-Polyoxometalate Dyads-Bipyridyl-Functionalized Polyoxometalates and Their Transition Metal Complexes
[DOI: 10.3390/molecules24244446]

S. Ullmann, P. Hahn, L. Blömer, A. Mehnert, C. Laube, B. Abel, B. Kersting*,
Dalton Trans. 2019, 48, 3893-3905.
Dinuclear Lanthanide Complexes Supported by a hybrid Salicylaldiminato/Calix[4]arene-Ligand: Synthesis, Structure, Magnetic and Luminescence Properties of (HNEt3)[Ln2(HL)(L)] (Ln = SmIII, EuIII, GdIII, TbIII)
[DOI: 10.1039/C9DT00292H]

J. Klose, A. Jeremies, T. Severin, D. Fuhrmann, J. Bergmann, J. Griebel, B. Abel, B. Kersting*,
Beilstein. J. Org. Chem. 2019, 15, 840-851.
Coordination Chemistry and photoswitching of dinuclear macrocyclic cadmium-, nickel-, and zinc complexes containing azobenzene carboxylato coligands
[DOI: 10.3762%2Fbjoc.15.81]

S. Gómez, M. Heindl, A. Szabadi, L. González*,
J. Phys. Chem. A 2019, 123, 8321-8332.
From Surface Hopping to Quantum Dynamics and Back. Finding Essential Electronic and Nuclear Degrees of Freedom and Optimal Surface Hopping Parameters
[DOI: 10.1021/acs.jpca.9b06103]

A. Winter, U. S. Schubert*,
Mater. Chem. Front. 2019, 3, 2308-2325.
The supramolecular assemblies based on heteroatom-containing triangulenes
[DOI: 10.1039/C9QM00532C]

F. Strieth-Kalthoff, C. Henkel, M. Teders, A. Kahnt, W. Knolle, A. Gomez-Suarez, K. Dirian, W. Alex, K. Bergander, C. G. Daniliuc, B. Abel, D. M. Guldi*, F. Glorius*,
Chem. 2019, 5, 2183-2194.
Discovery of Unforeseen Energy-Transfer-Based Transformations Using a Combined Screening Approach
[DOI: 10.1016/j.chempr.2019.06.004]

S. Straub, L. I. Domenianni, J. Lindner, P. Vöhringer*,
J. Phys. Chem. B 2019, 123, 7893−7904.
Photoinduced Dynamics of a Diazidocobalt(III) Complex Studied by Femtosecond UV-Pump/IR-to-Vis-Probe Spectroscopy
[DOI: 10.1021/acs.jpcb.9b07210]

L. I. Domenianni, R. Fligg, A. Schäfermeier, S. Straub, J. Beerhues, B. Sarkar*, P. Vöhringer*,
Phys.Chem.Chem.Phys. 2019, 21, 20393-20402.
Molecular and electronic structure of an azidocobalt(III) complex derived from X-ray crystallography, linear spectroscopy and quantum chemical calculations
[DOI: 10.1039/c9cp04350k]

B. Sarkar*, P. Vöhringer*, K. Heinze, C. Förster,
Nachr. Chem. 2019, 67, 67-71.
Photochemie: Bindungen aktivieren und Redoxreaktionen
[DOI: 10.1002/nadc.20194090185]

C. Förster, B. Sarkar, P. Vöhringer, K. Heinze*,
Nachr. Chem. 2019, 67, 54-59.
Photochemie: Licht und Leuchten bei 3d-Metallen
[DOI: 10.1002/nadc.20194089001]

J. Steube, L. Burkhardt, A. Päpcke, J. Moll, P. Zimmer, R. Schoch, C. Wölper, K. Heinze, S. Lochbrunner, M. Bauer*,
Chem. Eur. J. 2019, 25, 11826-11830.
Excited state kinetics of an air-stable cyclometalated iron(II) complex
[DOI: 10.1002/chem.201902488]

S. Preiß, A. Päpcke, L. Burkhardt, L. Großmann, S. Lochbrunner, M. Bauer, T. Opatz, K. Heinze,
Chem. Eur. J. 2019, 25, 5940-5949
Gold(II) Porphyrins in Photoinduced Electron Transfer Reactions
[DOI: 10.1002/chem.201900050]

S. Kreft, M. Sonneck, H. Junge, A. Päpcke, A. Kammer, C. Kreyenschulte, S. Lochbrunner, S. Wohlrab, M. Beller*,
Int. J. Hydrogen Energ. 2019, 44, 31892-31901.
Light-driven proton reduction with in situ supported copper nanoparticles
[DOI: 10.1016/j.ijhydene.2019.10.052]

2018

M.-A. Schmid, M. Rentschler, W. Frey, S. Tschierlei, M. Karnahl,
Inorganics 2018, 6, 134.
Imidazo-Phenanthroline Ligands as a Convenient Modular Platform for the Preparation of Heteroleptic Cu(I) Photosensitizers
[DOI: 10.3390/inorganics6040134]

M. Neugebauer, S. Schmitz, M. Krause, N. L. Doltsinis, A. Klein*,
Open Chemistry 2018, 16, 1214‒1226.
Reactions of the organoplatinum complex [Pt(cod)(neoSi)Cl] (neoSi = trimethylsilylmethyl) with the non-coordinating anions SbF6 and BPh4
[DOI: 10.1515/chem-2018-0130]

A. Friedrich, O. S. Bokareva, S.-P. Luo, H. Junge, M. Beller, O. Kühn, S. Lochbrunner,
Chem. Phys. 2018, 515, 557-563.
Effective quenching and excited-state relaxation of a Cu(I) photosensitizer addressed by time-resolved spectroscopy and TDDFT calculations
[DOI: 10.1016/j.chemphys.2018.08.048]

L. Suntrup, F. Stein, G. Hermann, M. Kleoff, M. Kuss-Petermann, J. Klein, O. S. Wenger, J. C. Tremblay, B. Sarkar,
Inorg. Chem. 2018, 57, 3973–13984.
Influence of Mesoionic Carbenes on Electro- and Photoactive Ru and Os Complexes: A Combined (Spectro-)Electrochemical, Photochemical, and Computational Study
[DOI: 10.1021/acs.inorgchem.8b02551]